Cross Section of Kloof Mine
(Figure from van Heerden, 2001)
Simplified geological cross section of the Kloof mining property,
west Wits line, showing levels 39, 41 and 43. The youngest stratagraphic
formation is the 2.4 Ga Pretoria group siliclastic sediments and diabase
sills (fed by the Running Dyke?). This overlies the 2.5 Ga Malmani
Dolomite which is a principal aquifer in the region and at Libanon is unconfined,
but at 4 shaft is confined. The dolomite overlies the 2.7 Ga Ventersdorp
volcanics and the contact is marked by the "Black Reef". The
Ventersdorp volcanics overlie the 2.9 Ga Central Rand Group of the Witwatersrand
Supergroup and the contact is marked by the VCR. The Central Rand
contain the MR and the Carbon leader. All of the deeper levels at
4 shaft mine the VCR, but 39 level also mines the CL of the Central Rand
Group. Shaft 7 of Kloof is just a few kilometers west of the 4 shaft
and a sample was collected from the 39 level there, presumably at about
the same depth as 39 level in 4 shaft. The strata are partitioned
into "compartments" by dykes of varying ages. The 1.4 Ga syenite
dikes radiating from the Pilansberg Complex (within the Bushveld Complex)
to the north cut all formations (Venterspost and Kloof dykes). Water from
the dolomite enters into the underlying Witwatersrand beds primarily through
fissures arranged en echelon to these dike aquicludes. Running dyke
must be ca. Transvaal in age or perhaps 2.0 Ga? The dykes associated
with Danies Fault and perhaps the Glenharvie dykes are Ventersdrop in age
as they are all truncated at the contact with the overlying dolomites.
Faults are often associated with dykes and vice-versa dykes will follow
faults (any weakness in the crust). Finally, the Witpoortjie Fault
truncates the Wits strata and may be a 2.0 Ga fault. If so it should
come to surface ca. 10 km south of Glenharvie. If this fault separates
basement gneiss from the Wits strata, then it may act as a conduit for
deeper fluids that may feed the subvertical fractures associated with the
dykes.
Map of 41 to 45 Levels of 4 Shaft Complex-Kloof Mine
(Figure from van Heerden, 2001)
The biggest water intersection in mine history-41 Level 56 Hanging Wall Drive South
The very first set of samples collected from Kloof were taken from 41
level 56 hanging wall drive south (K441 FW1 and 1a) and from 41 level 53
hanging wall drive north (K441FW2). More recently, these sites have
been resampled. Danies fault zone was also sampled recently at 43
level.
Samples KL441FW56HWDS come from fractures adjacent to the Glenharive Dyke. When first encountered while cover drilling during tunnel advancement several months prior to our first sampling, the flow rates were 100,000 liters/hour. It took a week just to put a valve on this one borehole. Several other boreholes were drilled through cased valves and more water encountered. A tracer test was performed using a fluorescent dye to test the connectivity of different boreholes. The fractures believed to be responsible for the water are illustrated as dashed blue lines beyond the tunnel face. Approximately 7 tons of chemically treated concrete were injected into these holes prior to our first sampling (blue boreholes) in '98. Subsequent to sampling the head of the tunnel was advance another 3 meters. No further advancement is planned. Ventilation is generally shut off now. Subsequent samples have come from other boreholes (red).
Kloof-Aqueous Geochemistry, Dissolved Gas and Microbial Results
The tables below list data available for samples of fissure water collected from Kloof mine, service water collected from Kloof mine and dolomite water collected from the IPC chamber from shaft 4 of Driefontein mine. The analyses are ordered from right to left according to the salinity, with the fresh intersection at 4 shaft Kloof, 43 level being the most saline (approximately 2% wt).
The data include field measurements of pH, pe, dissolved O2, temperature, conductivity, and water and gas flow rates. The number of microbial cells, as detected by flow cytometry (detection limit <5 x 103 cells/ml), are reported. The types of microorganisms that have been successfully cultivated in the laboratory at room temperature (viewed as contaminants with the exception of the dolomite water), 60oC (thermophiles) and 80oC (hyperthermophiles). SRB are sulfate reducing bacteria. Het. are heterotrophic (organic carbon utilizers). Me are methanogens. IRB are Fe(III) reducing bacteria. Sox are sulfide oxidizing bacteria. Thio. are thiosulfate oxidizing bacteria. The TOC is total organic carbon , followed by specific carboxylic acids commonly utilized by bacteria. CO2 represents the total inorganic carbon. The organic and inorganic carbon species are still being determined for all Kloof samples. These analyses are followed by the anions, major cations and the trace metals. The last part of the table represents the calculated saturation levels, of S.I. of various minerals. S.I. = 0 means the mineral is at saturation. S.I. > 0 means the mineral phase will form a precipitate. S.I. < 0 means the mineral phase will dissolve.
Fissure water is most readily distinguished from service water by the relative proportions of anions. Service water is low in chloride relative to bromide, high in sulfate (due to sulfide oxidation) and high in nitrate (due to explosives). Fissure water is largely comprised of Na, Ca and Cl. Fissure water is typically saturated with respect to calcite and this is consistent with observations of calcite filling water-bearing fractures. Fissure water typically contains no dissolved O2, with the exception of samples collected from shaft 4, level 41, hanging wall drive south. This presence of O2 in the samples may either indicate that this is a hybrid mixture of surface water and deep fissure water, or it may reflect the difficulty in packing off the boreholes at this locality. Air contamination can also be seen in the gas samples (see Sherwood-Lollar data). We will be returning to this location again to with packers designed to match borehole sizes in order to test whether the water is aerobic or anaerobic. Samples associated with Danies fault, however, are demonstrably anaerobic. The most saline , anaerobic fissure water do yield thermophilic and hyperthermophilic microorganisms, but do not yield room temperature microorganisms. This indicates the precautions taken in the field and lab to avoid contamination have been largely successful.
| SampleName |
IPC#4 120900
|
KL441SW 022801
|
KL441FW 050201 XC56HWDS hole 1
|
KL441FW 050201 XC56HWDS hole 2
|
KL441FW 022801 HWDN
|
KL441DB 022801 53EXC
|
KL739FW 062901
|
KL443FW 050801 XC43 HWDN
|
| Depth (kmbls.) |
0.945
|
3.3
|
3.3
|
3.3
|
3.3
|
3.3
|
3.1?
|
3.44?
|
| pH |
7.5
|
N.A.
|
12.5
|
8.4
|
8.7
|
5.5
|
5.8
|
8.2
|
| Eh (mv) |
N.A.
|
N.A.
|
N.A.
|
-260
|
N.A.
|
N.A.
|
-220
|
-300
|
| pe |
|
|
|
-3.98 (-5.4)
|
|
|
-3.39
|
-4.55 (-5.13)
|
| Cond. (mS/cm) |
N.A.
|
N.A.
|
6.8
|
5.3
|
N.A.
|
N.A.
|
N.A.
|
25 at RT
|
| ToC |
26
|
N.A.
|
50
|
56
|
49
|
N.A.
|
54
|
59
|
| O2 (ppm) |
0
|
N.A.
|
3
|
0
|
2
|
N.A.
|
0
|
0
|
| Alkalinity (ppm) |
>100
|
N.A.
|
>100
|
>100
|
N.A.
|
N.A.
|
N.A.
|
12
|
| Water Flow Rate (ml/min) |
|
N.A.
|
725
|
17,650
|
1000
|
3.5 to 4.0
|
9,000
|
22,200
|
| Gas Flow Rate (ml/min) |
|
N.A.
|
nil
|
214
|
nondetected
|
none
|
10,000
|
2,600
|
| Microbial Properties |
|
|
|
|
|
|
|
|
| Direct Counts 04/01 (cells/ml) |
?
|
N.A.
|
|
?
|
?
|
2e7
|
?
|
?
|
| Direct Counts 08/01(cells/ml) |
|
N.A.
|
|
<5e3
|
<5e3
|
|
1e4?
|
<5e3
|
| MPN's (cells/ml) |
>1e2
|
N.A.
|
|
>1
|
|
|
>1
|
>1
|
| Positive Enrichments 80oC |
N.A.
|
N.A.
|
|
Me33, Dil. Het.27, 32, IRB
|
N.A.
|
|
|
Dil. Het.24,29, SRB
|
| Positive Enrichments 60oC |
N.A.
|
N.A.
|
|
Me9, SRB14, IRB12
|
N.A.
|
|
SRB, Thio.
|
Me10, SRB8, Dil. Het.16
|
| Positive Enrichments Room T |
Sox, Thio.
|
N.A.
|
|
IRB21
|
N.A.
|
|
|
|
| Anions & Cations (ppm) |
|
|
|
|
|
|
|
|
| TOC |
29
|
N.A.
|
130.0
|
5.5
|
N.A.
|
N.A.
|
5.9
|
20.0
|
| acetate |
|
|
|
|
|
|
|
|
| propionate |
|
|
|
|
|
|
|
|
| formate |
|
|
|
|
|
|
|
|
| CO2 Total (Chemnet) |
>100
|
N.A.
|
<10
|
<10
|
N.A.
|
N.A.
|
N.A.
|
<10
|
| HCO3- |
|
|
|
|
|
|
|
|
| F |
0.44
|
N.D.
|
0.11
|
0.48
|
1.35
|
N.D.
|
1.53
|
3.75
|
| Cl |
14.01
|
197.45
|
1,221.37
|
1,563.32
|
5,073.16
|
7,609.34
|
8,184.92
|
12,494.88
|
| Br |
N.D.
|
11.92
|
6.18
|
7.5
|
15.78
|
37.78
|
47.04
|
45.91
|
| SO42- |
71.38
|
669.54
|
30.91
|
6.14
|
50.74
|
79.03
|
6.27
|
149.2
|
| HS- (Chemnet) |
<0.1
|
N.A.
|
0
|
0.4
|
0.4
|
N.A.
|
N.A.
|
1.5
|
| NO3- |
N.D.
|
18.27
|
0.06
|
N.D.
|
0.13
|
N.D.
|
N.D.
|
0.01
|
| NO2- |
N.D.
|
N.D.
|
N.D.
|
N.D.
|
0.26
|
0.27
|
N.D.
|
N.D.
|
| NH3 (Chemnet) |
<.1
|
N.A.
|
0
|
0.2
|
N.A.
|
N.A.
|
3
|
5
|
| PO43- |
N.D.
|
N.D.
|
0.05
|
0.03
|
N.D.
|
N.D.
|
N.D.
|
N.D.
|
| Total P as PO43- |
1.291
|
1.08
|
3
|
4.2
|
0.913
|
9.05
|
4.65
|
4.3
|
| Li |
N.D.
|
0.12
|
0.421
|
0.423
|
1.9
|
2.2
|
1.36
|
1.84
|
| Na |
18.20
|
157.00
|
384.00
|
452.00
|
1,865.00
|
2,025.00
|
1,680.00
|
2,580.00
|
| Mg |
42.6
|
39.35
|
N.D.
|
N.D.
|
4.75
|
4.22
|
0.15
|
0.105
|
| K |
2.2
|
11.6
|
13.9
|
8.69
|
33.9
|
37.1
|
41.4
|
52.2
|
| Rb |
N.A.
|
N.A.
|
0.121
|
0.114
|
N.A.
|
N.A.
|
0.173
|
0.248
|
| Ca |
56.25
|
250.00
|
595.00
|
458.00
|
1,965.00
|
2,122.40
|
2,800.00
|
3,280.00
|
| Sr |
0.1
|
1.465
|
7.8
|
8.5
|
39.2
|
44.4
|
90
|
46.3
|
| Ba |
0.11
|
0.049
|
0.26
|
0.038
|
0.8
|
0.835
|
2.09
|
0.581
|
| Al |
1.37
|
0.83
|
0.561
|
0.048
|
0.655
|
0.88
|
0.36
|
0.091
|
| Si |
11.2
|
13.8
|
1.16
|
18.9
|
16.9
|
17.6
|
12.2
|
11.3
|
| Mn |
0.06
|
0.11
|
N.D.
|
0.001
|
0.036
|
N.D.
|
0.0065
|
0.011
|
| Fe |
0.53
|
0.407
|
0.005
|
0.0035
|
1.466
|
0.556
|
0.01
|
0.005
|
| Fe(II) (Chemnet) |
N.A.
|
N.A.
|
0.1
|
0
|
0
|
N.A.
|
<1
|
0
|
| FeTotal (Chemnet) |
N.A.
|
N.A.
|
0.2
|
0.2
|
1
|
N.A.
|
N.A.
|
0
|
| Cr |
N.D.
|
N.D.
|
0.02
|
0.02
|
N.D.
|
0.03
|
0.016
|
0.022
|
| Co |
N.D.
|
0.07
|
0.0015
|
0.001
|
N.D.
|
N.D.
|
0.0025
|
0.0025
|
| Ni |
0.015
|
0.5
|
0.0125
|
0.0115
|
N.D.
|
N.D.
|
0.04
|
0.027
|
| Cu |
N.D.
|
N.D.
|
0.01
|
0.004
|
N.D.
|
N.D.
|
0.009
|
0.025
|
| Zn |
0.03
|
0.51
|
0.111
|
0.015
|
1.8
|
N.D.
|
0.019
|
0.03
|
| As |
N.D.
|
N.D.
|
0.08
|
0.087
|
N.D.
|
N.D.
|
0.011
|
0.105
|
| W |
N.D.
|
N.D.
|
|
|
N.D.
|
N.D.
|
|
|
| U |
N.D
|
0.15
|
0.06
|
0.067
|
N.D.
|
N.D.
|
0.2
|
0.15
|
| pCO2 |
|
|
|
-5
|
|
|
|
-4.9
|
| S.I.Calcite |
|
|
|
0.2
|
|
|
|
0.4
|
| S.I.Dolomite |
|
|
|
<-3
|
|
|
|
<-3
|
| S.I.Siderite |
|
|
|
<-3
|
|
|
|
<-3
|
| S.I.Quartz |
|
|
|
0.3
|
|
|
|
0.1
|
| S.I.Gibbsite |
|
|
|
-0.2
|
|
|
|
-0.9
|
| S.I.Gypsum |
|
|
|
-2.6
|
|
|
|
-1
|
| S.I.Barite |
|
|
|
-2.1
|
|
|
|
-0.3
|
| S.I.FeS |
|
|
|
-0.3
|
|
|
|
-0.2
|
| S.I.Fluorite |
|
|
|
-1.1
|
|
|
|
0.9
|
| Sample |
|
|
|
|
|
|
|
|
|
|
|
|
|
| KL441FW050201XC56HWDS hole 2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
| KL443FW030501HWND 1 |
|
|
|
|
|
|
|
|
|
|
|
|
|
| KL443FW050801XC43HWDN |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|||||||||||
| KL441FW1C56HWDS- Dec-98 |
|
|
|
|
|
|
|
|
|
|
|
|
|
| Notes: | |||||||||||||
| < d.l. = below detection limit | |||||||||||||
| LEL = Lower Explosive Limit | |||||||||||||
| n.a. = not analyzed | |||||||||||||
References:
van Heerden, A.W.C., A Lithological and Geomorphological Study of the
VCR Sand Facies observed within the 4-Shaft Complex, Kloof Gold Mine.
Unpublished Report.
West
Driefontein - East
Driefontein - Kloof - Beatrix
Fieldphotos
Witwatersrand
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